Appraisal of the adsorption potential of novel modified gellan gum nanocomposite for the confiscation of methylene blue and malachite green.

In the present investigation a novel, environmentally affable and economical, modified gellan gum nanocomposite (MAA-g-GG/Ppy/MMT) was fabricated via free-radical polymerization for the liquid-phase mitigation of Methylene blue (MB) and Malachite green (MG) dyes. The innovation of this work is substantiated by the intentional combination of diverse materials, the strategic incorporation of polypyrrole for enhanced adsorption, and the thoughtful addition of MMT as a nanofiller to address mechanical strength and improve adsorption capacity. The physico-chemical facets of MAA-g-GG/Ppy/MMT and its interaction with the dye molecules were elucidated using FT-IR, SEM-EDX, BET, TEM, and XRD techniques. The optimum conditions for the sorption of MB and MG were deemed to be dosage (1.2 g/L for both dyes), contact time (50 min for both dyes), initial MG/MB concentration (MB = 40 mg/L & MG = 30 mg/L), and pH (MB = 10 & MG = 7). The Freundlich isotherm was identified as the most suitable model, as evidenced by the highest R2 value (∼0.999), indicating multilayer adsorption. The pseudo second-order model appraised the kinetic data. Thermodynamic findings revealed the adsorption process to be spontaneous, viable and exothermic which was ascertained by negative ∆H⸰ values (-22.8 kJ/mol for MB and -18.3 kJ/mol for MG). The substantial Langmuir adsorption capacity (Qm: MG =185.185; MB = 344.827) can be ascribed to the reason for strong interactions between MAA-g-GG/Ppy/MMT and dyes. The high reliability of MAA-g-GG/Ppy/MMT was determined by the regeneration studies that worked up to four cycles for both dyes. The real water (distilled water, tap water, and river water) samples spiked with MG/MB demonstrated a substantial uptake of dyes (>85 %) and the marginal influence of ionic strength on the adsorptive potential of MAA-g-GG/Ppy/MMT validated its efficacy for the decontamination of real effluents. The forces of attraction between the dyes and MAA-g-GG/Ppy/MMT included van der Waals, electrostatic forces of attraction, and π-π interaction. This green, economical, and viable MAA-g-GG/Ppy/MMT will prove to be an efficient adsorbent for the decontamination process of sequestration of dyes to achieve a sustainable environment.

Synergistic effect of silver NPs immobilized on Fe3O4@L-proline magnetic nanocomposite toward the photocatalytic degradation of Victoria blue and reduction of organic pollutants.

The surface of magnetite (Fe3O4) nanoparticles was subject to modification through the incorporation of L-proline (LP) by simple co-precipitation method in which silver nanoparticles were deposited by in situ method, thereby yielding the Fe3O4@LP-Ag nanocatalyst. The fabricated nanocatalyst was characterized using an array of techniques including Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometry (VSM), Brunauer-Emmett-Teller (BET), and UV-Vis spectroscopy. The results evince that the immobilization of LP on the Fe3O4 magnetic support facilitated the dispersion and stabilization of Ag NPs. The SPION@LP-Ag nanophotocatalyst exhibited exceptional catalytic efficiency facilitating the reduction of MO, MB, p-NP, p-NA, NB, and CR in the presence of NaBH4. The rate constants obtained from the pseudo-first-order equation were 0.78, 0.41, 0.34, 0.27, 0.45, 0.44, and 0.34 min-1 for CR, p-NP, NB, MB, MO, and p-NA, respectively. Additionally, the Langmuir-Hinshelwood model was deemed the most probable mechanism for catalytic reduction. The novelty of this study lies in the use of L-proline immobilized on Fe3O4 MNPs as a stabilizing agent for the in-situ deposition of silver nanoparticles, resulting in the synthesis of Fe3O4@LP-Ag nanocatalyst. This nanocatalyst exhibits high catalytic efficacy for the reduction of multiple organic pollutants and azo dyes, which can be attributed to the synergistic effects between the magnetic support and the catalytic activity of the silver nanoparticles. The easy recyclability and low cost of the Fe3O4@LP-Ag nanocatalyst further enhance its potential application in environmental remediation.

A review on remediation of dye adulterated system by ecologically innocuous "biopolymers/natural gums-based composites".

The mitigation of wastewater exploiting biopolymers/natural gums-based composites is an appealing research theme in today's scenario. The following review presents a comprehensive description of the polysaccharides derived from biopolymers (chitosan, collagen, cellulose, starch, pectin, lignin, and alginate) and natural gums (guar, gellan, carrageenan, karaya, moringa oliefera, tragacanth, and xanthan gum). These biopolymers/natural gums-based composites depicted excellent surface functionality, non-toxicity, economic and environmental viability, which corroborated them as potential candidates in the decontamination process. The presence of -OH, -COOH, and -NH functional groups in their backbone rendered them tailorable for modification/functionalization, and anchor an array of pollutants via electrostatic interaction, hydrogen bonding, and Van der Waals forces. Further, due to these functional moieties, these bio-based composites revealed an excellent adsorption capacity than conventional adsorbents. This review provides an overview of the classification of biopolymers/natural gums based on their origin, different ways of their modification, and the remediation of dye-contaminated aqueous environments employing diverse bio-based adsorbents. The isotherm, kinetic modelling along with thermodynamics of the adsorption process is discussed. Additionally, the reusable efficacy of these bio-adsorbents is reviewed.